Decadal changes in vegetation cover within coastal dunes at the regional scale in Victoria, SE Australia.

Vegetation is a critical boundary condition for the stability of coastal dunes. Globally, vegetation cover is increasing on the coast with many dunes being stabilised in the past decades. This pattern is driven by site-specific (e.g., coastal management) and global (e.g., climatic changes) factors. This study examines changes in dune vegetation during the past six decades at the regional scale along the southeast coast of Australia to understand the relative importance of the climate and human interventions in vegetation cover change. A total area of >31,000 ha, comprising 53% of the open coast of Victoria was studied. Since the 1960's, a general trend of dune stabilisation and coastal greening has occurred with total vegetation cover increasing from 61% to 84% coverage until 2020. At the regional scale, the increase in vegetation cover has been primarily driven by both climatic-related drivers, such as rising temperature, elevating CO2 concentrations and declining windiness, and state-wide coastal management interventions (e.g., marram grass planting, fencing, fire control, grazing removal). The only areas where there was a decline in total area of vegetation was where substantial coastal recession had occurred. The decrease in vegetation is a result of a loss of land area rather than a loss of plant biomass over the dunefields. Therefore, it is considered that the overall decadal changes in both climate and coastal management are forcing the dunes toward a more stabilised state at the regional scale. At the same time, compelling local drivers (e.g., storms and local sediment deficiency) can be the most crucial factor to regulate vegetation change and shift dune mobility at the site-specific scale.

Composite substrate of graphene/Ag nanoparticles coupled with a multilayer film for surface-enhanced Raman scattering biosensing.

In this paper, we designed a surface-enhanced Raman scattering (SERS) substrate for graphene/Ag nanoparticles (Ag NPs) bonded multilayer film (MLF) using the hybrid nanostructures composed of graphene and plasmonic metal components with significant plasmonic electrical effects and unique optical characteristics. This paper achieved the advantages of efficient utilization of electromagnetic field and reduction of fluorescence background based on the electromagnetic enhancement activity of Ag NPs and unique physical/chemical properties of graphene with zero gap structures. Au/Al2O3 was stacked periodically to construct MLF. As indicated by the electric field intensity at the Au/Al2O3 interface of the respective layer, bulk plasmon polariton (BPP) in the MLF was excited and coupled with localized surface plasmon (LSP) in the Ag NPs, which enhanced the electromagnetic field on the top-layer of SERS substrate. To measure the performance of the SERS substrate, rhodamine 6G (R6G) and malachite green (MG) were used as the probe molecules, with the detection limits of 10-11 M and 10-8 M, respectively. The SERS substrate had high sensitivity and uniformity, which indicated that it has a broad application prospect in the field of molecular detection.

LSPR optical fiber sensor based on 3D gold nanoparticles with monolayer graphene as a spacer.

Localized surface plasmon resonance (LSPR) optical fiber biosensing is an advanced and powerful label-free technique which gets great attention for its high sensitivity to refractive index change in surroundings. However, the pursuit of a higher sensitivity is still challenging and should be further investigated. In this paper, based on a monolayer graphene/gold nanoparticles (Grm/Au NPs) three-dimensional (3D) hybrid structure, we fabricated a D-shaped plastic optical fiber (D-POF) LSPR sensor using a facile two-step method. The coupling enhancement of the resonance of this multilayer structure was extremely excited by the surface plasmon property of the stacked Au NPs/Grm layer. We found that the number of plasmonic structure layers was of high importance to the performance of the sensor. Moreover, the optimal electromagnetic field enhancement effect was found in three-layer plasmonic structure. Besides, the n*(Grm/Au NPs)/D-POF sensor exhibited outstanding performance in sensitivity (2160 nm/RIU), linearity (linear fitting coefficient R2 = 0.996) and reproducibility. Moreover, the sensor successfully detected the concentration of glucose, achieving a sensitivity of 1317.61 nm/RIU, which suggested a promising prospect for the application in medicine and biotechnology.

Surface-enhanced Raman scattering by the composite structure of Ag NP-multilayer Au films separated by Al2O3.

In the present study, a nanoparticle-multilayer metal film substrate was presented with silver nanoparticles (Ag NPs) assembled on a multilayer gold (Au) film by employing alumina (Al2O3) as a spacer. The SERS performance of the proposed structures was determined. It was suggested that the SERS effect was improved with the increase in the number of layers, which was saturated at four layers. The SERS performance of the structures resulted from the mutual coupling of multiple plasmon modes [localized surface plasmons (LSPs), surface plasmon polaritons (SPPs), as well as bulk plasmon polaritons (BPPs)] generated by the Ag NP-multilayer Au film structure. Furthermore, the electric field distribution of the hybrid system was studied with COMSOL Multiphysics software, which changed in almost consistency with the experimentally achieved results. For this substrate, the limit of detection (LOD) was down to 10-13 M for the rhodamine 6G (R6G), and the proposed SERS substrate was exhibited prominently quantitatively detected capability and high reproducibility. Moreover, a highly sensitive detection was conducted on toluidine blue (TB) molecules. As revealed from the present study, the Ag NP-multilayer Au film structure can act as a dependable SERS substrate for its sensitive molecular sensing applications in the medical field.

ZrSe2 nanosheet as saturable absorber for soliton operations within an Er-doped passive mode-locked fiber laser.

Two-dimensional materials have extensively promoted the development of ultrafast photonics in the past decade. In our work, the saturable absorption properties of ZrSe2 were presented. The saturation intensity, modulation depth, and nonlinear absorption coefficient of the ZrSe2 saturable absorber (SA) are about 13.14MW/cm2, 6.09%, and 1.85∗10-1cm/GW. In the experiment, based on the ZrSe2 SA, two types of solitons were recorded. A conventional soliton with a pulse width of 985 fs and a three-pulse bound state soliton have been obtained. Our experiment reveals that ZrSe2 can be employed for generating multiple ultrafast soliton generations and possess promising application in ultrafast photonics.

CVD-Bi2Te3 as a saturable absorber for various solitons in a mode-locked Er-doped fiber laser.

In this work, we report about high energy and various solitons' operation by using high-efficiency topological insulator bismuth telluride (Bi2Te3) nanofilms as broadband saturable absorbers in the passively mode-locked Er-doped fiber laser. The Bi2Te3 film was successfully synthesized by chemical vapor deposition (CVD). Excellent characteristics of the dark-bright pulse pairs, bright pulses, and multiharmonics have been investigated experimentally by adjusting the polarization state. At the same time, the maximum average output power was 40.18 mW, and the single-pulse energy was 20.91 nJ. As we all know, it is the various solitons of the first generation with large pulse energy in an Er-doped fiber laser with Bi2Te3 as saturable absorber. The experimental results show that CVD Bi2Te3 can be used as an excellent candidate in mode-locked fiber lasers.

Generation of high-energy rectangular pulses in a nonlinear polarization rotation mode-locked ring fiber laser.

In this paper, a novel high-energy mode-locked fiber laser based on the nonlinear polarization rotation (NPR) technique is presented to generate 331 nJ rectangular pulses. When pump power was 2659 mW, the maximum output power would be 102.3 mW; the maximum peak power was 41.74 W under the pump power of 1766 mW. In this study, the use of two homemade laser diodes and other common fiber devices was a vital step to achieve the low-cost and high-efficiency NPR mode-locked fiber laser. Based on these results, a novel approach could be developed to realize a high-energy rectangular pulse and promote the practical applications of the NPR mode-locked fiber laser in the field of ultrafast photonics.

Output energy enhancement in a mode-locked Er-doped fiber laser using CVD-Bi2Se3 as a saturable absorber.

In this study, the output energy in topological insulators (TIs)-based Erbium-doped fiber laser (EDFL) was improved using two strategies: bidirectional pumped laser cavity and saturable absorber (SA) with high damage threshold and large modulation depth. Using the chemical vapor deposition (CVD) method, Bismuth Selenide (Bi2Se3) film was synthesized and improved to a SA. Employing this CVD-Bi2Se3 SA in an EDFL, bright and bright-dark soliton operations were achieved. The average output power/pulse energy was 82.6 mW/48.3 nJ and 81.2 mW/47.5 nJ, respectively. The results demonstrate that CVD-Bi2Se3 can act as an excellent performance material to improve output power performance in TISA-based EDFL.

Noise-like mode-locked Yb-doped fiber laser in a linear cavity based on SnS2 nanosheets as a saturable absorber.

In this study, a high-energy noise-like mode-locked Yb-doped fiber laser in a linear cavity was achieved with SnS2-polyvinyl alcohol film as the saturable absorber. In addition, the nonlinear saturable absorption characteristics of the SnS2 were investigated experimentally. The saturation intensity and modulation depth were about 6.01 MW/cm2 and 8.68%, respectively. Under pump power of 422 mW, stable noise-like mode-locked operation with a maximum output power and largest single pulse energy of 9.50 mW and 18.1 nJ, respectively, was obtained. To the best of our knowledge, this study is the first to observe and experimentally investigate noise-like operation in a linear laser cavity. Our study may provide some valuable design guidelines for noise-like operation and create new directions for advanced photonic devices based on SnS2.

Improved Laser Damage Threshold of In2Se3 Saturable Absorber by PVD for High-Power Mode-Locked Er-Doped Fiber Laser.

In this study, a double-end pumped high-power passively mode-locked erbium-doped fiber laser (EDFL) was realized by employing a few-layered In2Se3 flakes as a saturable absorber (SA). Herein, the uniform large-scale In2Se3 flakes were synthesized by the physical vapor deposition (PVD) method. The PVD-In2Se3 SA exhibited a remarkable damage threshold of higher than 24 mJ/cm2. Meanwhile, the PVD-In2Se3 SA had a modulation depth and saturable intensity of 18.75% and 6.8 MW/cm2, respectively. Based on the In2Se3 SA, the stable bright pulses emitting at 1559.4 nm with an average output power/pulse energy/pulse duration of 122.4 mW/5.8 nJ/14.4 ns were obtained successfully. To our knowledge, 122.4 mW was the new major breakthrough of mode-locked Er-doped fiber lasers. In addition, this is the first demonstration of the dark-bright pulse pair generation based on In2Se3 SA. The maximum average output power of the dark-bright pulse reached 121.2 mW, which also showed significant enhancement in comparison with previous works. Our excellent experiment results fully prove the superiority of our experimental design scheme and indicate that the PVD-In2Se3 could operate as a promising highly-nonlinear photonic material for a high-power fiber laser.

Large-energy mode-locked ytterbium-doped linear-cavity fiber laser based on chemical vapor deposition-Bi2Se3 as a saturable absorber.

We reported on the generation of pulse bunch and large-energy dark pulses in a mode-locked ytterbium-doped linear-cavity fiber laser based on Bi2Se3 as a saturable absorber (SA). Bi2Se3 nanosheets were successfully synthesized by the chemical vapor deposition (CVD) method and transferred to the end facet of a fiber connector for the proposed SA. Its saturation intensity and modulation depth were measured to be 52 MW/cm2 and 14.5%, respectively. By inserting the Bi2Se3-based SA into the Yb-doped all-fiber linear cavity, stable pulse bunches were observed. In addition, dark soliton operation with a maximum average output power of 32.6 mW and a pulse energy of 61.8 nJ were also achieved. To the best of our knowledge, this is the first demonstration of a dark soliton within a linear cavity with much larger pulse energy than previous works. Our study fully indicated that CVD-Bi2Se3 could be an excellent SA for achieving large-energy pulse operations.

Versatile Mode-Locked Operations in an Er-Doped Fiber Laser with a Film-Type Indium Tin Oxide Saturable Absorber.

We demonstrate the generation of versatile mode-locked operations in an Er-doped fiber laser with an indium tin oxide (ITO) saturable absorber (SA). As an epsilon-near-zero material, ITO has been only used to fashion a mode-locked fiber laser as an ITO nanoparticle-polyvinyl alcohol SA. However, this type of SA cannot work at high power or ensure that the SA materials can be transmitted by the light. Thus, we covered the end face of a fiber with a uniform ITO film using the radio frequency magnetron sputtering technology to fabricate a novel ITO SA. Using this new type of SA, single-wavelength pulses, dual-wavelength pulses, and triple-wavelength multi-pulses were achieved easily. The pulse durations of these mode-locked operations were 1.67, 6.91, and 1 ns, respectively. At the dual-wavelength mode-locked state, the fiber laser could achieve an output power of 2.91 mW and a pulse energy of 1.48 nJ. This study reveals that such a proposed film-type ITO SA has excellent nonlinear absorption properties, which can promote the application of ITO film for ultrafast photonics.

Linkages between the spatial toxicity of sediments and sediment dynamics in the Yangtze River Estuary and neighboring East China Sea.

Anthropogenic activities are driving an increase in sediment contamination in coastal areas. This poses significant challenges for the management of estuarine ecosystems and their adjacent seas worldwide. However, few studies have been conducted on how dynamic mechanisms affect the sediment toxicity in the estuarine environment. This study was designed to investigate the linkages between sediment toxicity and hydrodynamics in the Yangtze River Estuary (YRE) area. High sediment toxicity was found in the Yangtze River mouth (Region I), the depocenter of the Yangtze River Delta (Region II), and the southeastern area of the adjacent sea (Region III), while low sediment toxicity was found in the northeastern offshore region (Region IV). A spatial comparison analysis and regression model indicated that the distributed pattern of sediment toxicity was likely related to hydrodynamics and circumfluence in the East China Sea (ECS) shelf. Specifically, high sediment toxicity in Region I may be affected by the Yangtze River Pump (YRP) and the low hydrodynamics there, and high toxicity in Region II can be influenced by the low sediment dynamics and fine sediment in the depocenter. The high sediment toxicity in Region III might be related to the combination of the YRP and Taiwan Warm Current, while the low toxicity in Region IV may be influenced by the local coarse-grained relict sand with strong sediment dynamics there. The present research results further suggest that it is necessary to link hydrodynamics and the spatial behavior of sediment and sediment-derived pollutants when assessing the pollution status of estuarine environments, especially for those mega-estuaries and their neighboring ocean environments with complex waves, tides and ocean currents.

Variations of sediment toxicity in a tidal estuary: a case study of the South Passage, Changjiang (Yangtze) Estuary.

Sediments in estuaries, especially those containing a large reservoir of contaminants released from urban and industrial activities, have had great impacts on benthic fauna and associated species. A better understanding of the toxicity of contaminants in estuarine sediments is of great significance to ecological assessments. Here, based on the collected sediments from neap to spring tides in the South Passage, Changjiang Estuary, the toxicity of the sediments was first studied using the frog embryo teratogenesis assay-Xenopus (FETAX). The results showed that the extracts of estuarine sediments induced multiple malformations in the embryos and that the phenotypes of malformation had two distinct patterns of variations corresponding to the tidal cycles. The phenotypes in the first pattern were dominated by hypopigmentation and edema of the heart, and the pattern was mainly controlled by fine-grained fractions. The phenotypes in the second pattern were dominated by edema of the heart and enlarged proctodeum, and it was mostly controlled by coarse-grain fractions. The sediment toxicity was higher during the spring and flood tides, which may be influenced by the grain size and sediment resuspension. Furthermore, obvious periodicities existed in the changes of the percentages of hatching (14-16 h and 6 h), enlarged proctodeum (15-18 h), and bent tail (5-7 h) due to the influence of tidal cycles. Moreover, our results also suggested that FETAX is an appropriate cost-effective biological monitoring tool to assess estuarine ecological health in contaminated sediments.

Use of the enhanced frog embryo teratogenesis assay-Xenopus (FETAX) to determine chemically-induced phenotypic effects.

The frog embryo teratogenesis assay-Xenopus (FETAX) is an established method for the evaluation of the developmental toxicities of chemicals. To develop an enhanced FETAX that is appropriate for common environmental contaminants, we exposed Xenopus tropicalis embryos to eight compounds, including tributyltin, triphenyltin, CdCl2, pyraclostrobin, picoxystrobin, coumoxystrobin, all-trans-retinoic acid and 9-cis-retinoic acid. Multiple malformations were induced in embryos particularly following exposure to tributyltin, triphenyltin and pyraclostrobin at environmentally relevant concentrations. Based on the range of observed malformations, we proposed a phenotypic assessment method with 20 phenotypes and a 0-5 scoring system. This derived index exhibited concentration-dependent relationships for all of the chemicals tested. Furthermore, the phenotype profiles were characteristic of the different tested chemicals. Our results indicate that malformation phenotypes can be quantitatively integrated with the primary endpoints in conventional FETAX assessments to allow for increased sensitivity and measurement of quantitative effects and to provide indicative mechanistic information for each tested chemical.

[Optimize extraction technology of Fufang Bajitian Shenggu Particles by central composite design and response surface method].

OBJECTIVE: To optimize extraction process of Fufang Bajitian Shenggu Particles by central composite design and response surface method. METHODS: The preparation of Fufang Bajitian Shenggu Particles was designed according to the test. With the overall desirability (OD) of Icariin content and the dry extract yield in medicinal materials extract concentrate as examining indexes, immersion time, material liquid ratio, extraction time and stress concentration temperature were investigated. Based on the single factor tests, material liquid ratio, extraction time and stress concentration temperature which impacted response values significantly were investigated by three factors and five levels of central composite design. RESULTS: Optimum extraction technology of Fufang Bajitian Shenggu Particles were as follows: material liquid ratio was 1:11.33, extraction time was 39 min, and stress concentration temperature was 66 °C. Bias of the lcariin content and the dry extract yield between observed and predicted values were 1.60% and 1.55% ,respectively. CONCLUSIONS: Using central composite design and response surface method to optimize extraction of Fufang Bajitian Shenggu particles has a good prediction.